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Effects of Nitrification Inhibitors on Mineral Nitrogen Dynamics in Agriculture Soils

机译:硝化抑制剂对农业土壤矿质氮动态的影响

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Experiments were conducted under laboratory conditions to elucidate the effect of three nitrification inhibitors viz, 3.4dime-thylpyrazo-lephosphate (DMPP), 4-Chlormethylpyrazole (ClMP) and dicyandiamide (DCD) on mineral nitrogen dynamics of (NH 4 ) 2 SO 4 in soil incubated at 25 o C in soils. The quantitative determination of ammonium, nitrite and nitrate were carried out spectrophotometrically, while potential denitrify-cation capacity (PDC) was measured gas chromatographically. DMPP, ClMP and DCD were used on recommended rates of 90kg N ha -1 corres-ponding to 0.36μg DMPP; 0.25μg ClMP and 10μg DCD g -1 dry soil. In all treatments, the influence of 1, 10, 50, 100, 250 and 500 times of the recommended-concentrations were examined. Results suggested that DMPP, ClMP and DCD applied at rates generally recommended for agricultural use may not be effective to inhibit nitrification. Thus even at the highest tested NIs-concentrations, nitrate and nitrite formation still occurred. Application of high concentrations of these chemicals up to 180μg DMPP, 125μg ClMP and 2500μg DCD were needed for inhibiting nitrification completely. The three NIs began to inhibit PDC at 10 to 50 times recommended concentration and were more effective in sandy than in loamy or clay soils. ClMP influenced PDC at much lower concentration as DMPP or DCD. ? Keywords: nitrification inhibitors, mineral nitrogen dynamics Normal 0 false false false EN-US X-NONE X-NONE
机译:在实验室条件下进行了实验,以阐明三种硝化抑制剂,即3.4dime-吡唑并唑磷酸盐(DMPP),4-氯甲基吡唑(ClMP)和双氰胺(DCD)对(NH 4)2 SO 4矿物氮动力学的影响。在25 o C的土壤中孵育的土壤。分光光度法对铵,亚硝酸盐和硝酸盐进行定量测定,气相色谱法测定潜在的反硝化阳离子容量(PDC)。 DMPP,ClMP和DCD的建议用量为90kg N ha -1,对应于0.36μgDMPP; 0.25μgClMP和10μgDCD g -1干燥土壤。在所有处理中,均检查了推荐浓度的1、10、50、100、250和500倍的影响。结果表明,DMPP,ClMP和DCD的推荐使用量通常建议用于农业用途,可能无法有效抑制硝化作用。因此,即使在测试的最高NIs浓度下,仍会发生硝酸盐和亚硝酸盐形成。为了完全抑制硝化作用,需要使用高达180μgDMPP,125μgClMP和2500μgDCD的高浓度化学药品。这三个NIs开始以推荐浓度的10到50倍抑制PDC,并且在沙质中比在壤土或粘土中更有效。 ClMP以比DMPP或DCD低得多的浓度影响PDC。 ?关键字:硝化抑制剂,矿物氮动力学正常0假假假EN-US X-NONE X-NONE

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