Solution Plasma Process-Derived Defect-Induced Heterophase Anatase/Brookite TiO₂ Nanocrystals for Enhanced Gaseous Photocatalytic Performance

摘要

We report a simple room-temperature synthesis route for increasing the reactivity of a TiO_(2) photocatalyst using a solution plasma process (SPP). Hydrogen radicals generated from the SPP chamber interact with the TiO_(2) photocatalyst feedstock, transforming its crystalline phase and introducing oxygen vacancy defects. In this work, we examined a pure anatase TiO_(2) as a model feedstock because of its photocatalytic attributes and well-characterized properties. After the SPP treatment, the pure anatase crystalline phase was transformed to an anatase/brookite heterocrystalline phase with oxygen vacancies. Furthermore, the SPP treatment promoted the absorption of both UV and visible light by TiO_(2). As a result, TiO_(2) treated by the SPP for 3 h showed a high gaseous photocatalytic performance (91.1%) for acetaldehyde degradation to CO_(2) compared with the activity of untreated TiO_(2) (51%). The SPP-treated TiO_(2) was also more active than nitrogen-doped TiO_(2) driven by visible light (66%). The overall photocatalytic performance was related to the SPP treatment time. The SPP technique could be used to enhance the activity of readily available feedstocks with a short processing time. These results demonstrate the potential of this method for modifying narrow-band gap metal oxides, metal sulfides, and polymer composite-based catalyst materials. The modifications of these materials are not limited to photocatalysts and could be used in a wide range of energy and environment-based applications.