Luminescent Iridium(III) Chemosensor for Tandem Detection of F– and Al3+

摘要

A new highly sensitive luminescent iridium(III) chemosensor, 1 , was designed and synthesized for tandem detection of fluoride ions (F~(–)) and aluminum ions (Al~(3+)). This sensor 1 exhibited obvious luminesce quenching by hydrogen bond interactions with F~(–). In addition, the resulting 1-F complex can be further used to detect Al~(3+) through a luminesce enhancement. The detection limit (0.02 μM) of 1-F for Al~(3+) is far lower than the World Health Organization (7.41 μM) limit for drinking water. Importantly, chemosensor 1-F could be used to detect and quantify F~(–) and Al~(3+) reversibly. This sensor achieved rapid detection of two ions, which relies on only one probe.