Amphiphilic Copolymers Containing POSS and SBMA with N-Vinylcaprolactam and N-Vinylpyrrolidone for THF Hydrate Inhibition

摘要

Icelike gas hydrates deposited in the pipelines under low temperatures and high pressures could remarkably reduce the transport efficiency, and a low dosage of water-soluble polymers could act as kinetic hydrate inhibitors (KHIs) to prevent gas hydrate formation. It was believed that the hydrophobic moiety in the water-soluble polymers played a vital role in enhancing the KHI performance. In this work, amphiphilic copolymers containing hydrophobic polyhedral oligomeric silsesquioxane (POSS) and superhydrophilic sulfobetaine methacrylate (SBMA) as well as N-vinylcaprolactam (VCap) and N-vinylpyrrolidone (VP) were prepared, and an efficient effect of the obtained amphiphilic copolymers on tetrahydrofuran (THF) hydrate inhibition was found. When a certain amount of the amphiphilic copolymers was introduced, the THF hydrate as an analogue of structure II gas hydrates presented a prolonged induction time and gave rise to a looser state rather than a crystalline solid. Analyses of low-field nuclear magnetic resonance and differential scanning calorimetry verified that there were strong interactions between the copolymer and water molecules by incorporation of SBMA units, which could enhance the KHI properties of the prepared amphiphilic copolymers. Additionally, the hydrophobic POSS in the amphiphilic copolymers could possibly modulate the hydrophilic/hydrophobic balance, contributing to the synergistical ability of the copolymers for THF hydrate inhibition. It was suggested that the amphiphilic copolymers containing POSS and zwitterionic units with VCap or VP could have potential for the inhibition and antiaggregation of gas hydrates in the transportation pipelines.