Stability of the compounds with the octahedral [MII(κ3-L)2] coordination building blocks of late 3d elements via solvate water supramolecular arrangement

摘要

Five new coordination compounds with the common formulae [MII(bdmpza)2]?xH2O (bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate, C11H15N4COO-; x = 2 for Co (1), Ni (2) and Zn (3), x = 3 for Mn (4) and Fe (5)), were synthesized from the reaction mixtures conta