Structural Studies of Steric Effects in Phosphine Complexes: Dimers of Bis-{dithiocyanato(1-phenyl-dibenzophosphole)mercury(II)} Associate with Significant Hg?N and Hg?S Interdimer Interactions

摘要

The title compound, [Hg(SCN) 2 (C 6 H 5 )P(C 12 H 8 )] 2 , exists as a dimer with two-fold crystallographic symmetry in the solid state with the Hg atoms linked by bridging N- and S-thiocyanato atoms. There are four primary bonds to each...