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Functionality of Inorganic Nanostructured Materials onto Wool Fabric

机译:羊毛织物上无机纳米结构材料的功能

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Silver nanoparticles (AgNPs) were prepared through chemical reduction method and characterized by UV-Vis absorption spectra to examine its formation with different AgNO 3 and sodium borohydride concentrations and by transmission electron microscope (TEM) to evaluate its particle size and size distribution. The wool fabric was first treated separately with AgNPs and titanium dioxide nanoparticles (TiO 2 NPs) and then dyed with C.I. Acid Orange 74 (AO74). The dye uptake of pre-treated wool fabric with nanoparticles was compared to conventional dyeing of wool. The existence of AgNPs and TiO 2 NPs on wool fabric during acid dyeing increases the dye uptake up to 27 and 39%, respectively. The dyeing kinetic of wool fabric was positively affected by treating with AgNPs and TiO 2 NPs. Also, the activation energy of AO74 diffusion was calculated before and after NPs-treatment that confirms the physicsorption dyeing process. The NPs-treatment leads to produce a wool fabric with excellent antibacterial and photocatalytic properties for TiO 2 NPs-treated wool fabric and very good antibacterial and good photocatalytic properties for AgNPs-treated wool fabric. In addition, NPs-treatment has no adverse effects on fastness properties of the functionalized dyed wool fabric.
机译:通过化学还原法制备了银纳米颗粒(AgNPs),并通过紫外-可见吸收光谱对其进行了表征,以检测其在不同的AgNO 3和硼氢化钠浓度下的形成,并通过透射电子显微镜(TEM)评估其粒径和粒径分布。羊毛织物首先分别用AgNPs和二氧化钛纳米颗粒(TiO 2 NPs)处理,然后用C.I.酸性橙74(AO74)。将经预处理的具有纳米粒子的羊毛织物的染料吸收与常规的羊毛染色进行比较。酸性染色过程中,羊毛织物上存在AgNPs和TiO 2 NPs分别使染料吸收量增加27%和39%。 AgNPs和TiO 2 NPs处理对羊毛织物的染色动力学有积极影响。另外,在NPs处理之前和之后计算了AO74扩散的活化能,这证实了物理吸附染色过程。 NPs处理导致生产的羊毛织物对TiO 2 NPs处理的羊毛织物具有优异的抗菌和光催化性能,对AgNPs处理的羊毛织物具有非常好的抗菌和良好的光催化性能。另外,NPs处理对功能化的染色羊毛织物的坚牢度特性没有不利影响。

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