Photocatalytic Degradations of Malachite Green onMagnetically Separable Ni1-xCoxFe2O4 NanoparticlesSynthesized by Using a Hydrothermal Process

摘要

Ni_(1-x)Co_(x)Fe_(2)O_(4) (x=0–1.0) ferrite nanoparticles were synthesized by using a hydrothermal process. The nanoparticles had average particle sizes of 14.8?29.4 nm and a narrow band gap of 1.75?1.91 eV, decreasing with increasing Co content. The nanoparticles showed an excellent sunlight-excited photocatalytic activity to malachite green in water. Moreover, the addition of a small amount of H_(2)O_(2) resulted in an obviously enhanced photodegradation, indicating a Fenton-like reaction. The photodegradation and Fenton-like photodegradation rates increased with increasing Co content. Complete Co substitution for Ni resulted in an optimal effect. Quasi-kinetic rate constant k values were in the range of 2.23–7.2×10~(-2) min~(-1) and increased to 1.3–6.0×10~(-1) min~(-1) upon the addition of H_(2)O_(2). The measurement of oxidation-reduction potential of the nanoaprticles in the photodegradation condition indicated a reductive characteristic enhanced with increasing Co content. Furthermore, the nanoparticles possessed high saturation magnetizations of 50.7?64.2 emu?g~(?1) and low coercivity of 0.4?1.7 kOe, which ensured that they gave magnetic separable in finally degraded dye aqueous solution.