Convergent synthesis of a tetrasaccharide repeating unit of the O-specific polysaccharide from the cell wall lipopolysaccharide of Azospirillum brasilense strain Sp7

摘要

A straightforward convergent synthesis has been carried out for the tetrasaccharide repeating unit of the O -specific cell wall lipopolysaccharide of the strain Sp7 of Azospirillum brasilense . The target tetrasaccharide has been synthesized from suitably protected monosaccharide intermediates in 42% overall yield in seven steps by using a [2 + 2] block glycosylation approach.