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Adsorption of boron from aqueous solutions using activated carbon prepared from olive bagasse

机译:使用橄榄蔗渣制得的活性炭从水溶液中吸附硼

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摘要

In this study, activated carbon was prepared from olive bagasse by physical activation. The pore properties including the BET surface area, pore volume, pore size distribution and average pore diameter were characterized. BET surface area of the activated carbon was determined as 803 m~2g~(-1). In this study, boron removal from aqueous solutions by adsorption was investigated. In the batch mode adsorption studies, the effects of initial pH of solution, contact time, temperature and initial boron concentration of solution were examined. A comparison of kinetic models applied to the adsorption of boron onto activated carbon was evaluated for the pseudo-first order, pseudo-second order, intraparticle diffusion, Elovich and Bangham's kinetic models. The experimental data fitted the pseudo-first order and intraparticle diffusion kinetic model. The thermodynamic parameters were also calculated. In the isotherm studies, the Langmuir, Freundlich and Dubinin -Radushkevich (DR) isotherm models were applied. The results indicate that Freundlich and DR equations are well described with the adsorption data for boron adsorption.
机译:在这项研究中,活性炭是从橄榄蔗渣中通过物理活化制备的。表征了包括BET表面积,孔体积,孔径分布和平均孔径的孔性质。活性炭的BET表面积测定为803m〜2g〜(-1)。在这项研究中,研究了通过吸附从水溶液中除硼的方法。在间歇模式吸附研究中,检查了溶液的初始pH,接触时间,温度和溶液的初始硼浓度的影响。对于拟一级,拟二级,颗粒内扩散,Elovich和Bangham动力学模型,对应用于硼吸附到活性炭上的动力学模型进行了比较。实验数据拟合拟一阶和粒子内扩散动力学模型。还计算了热力学参数。在等温线研究中,应用了Langmuir,Freundlich和Dubinin -Radushkevich(DR)等温线模型。结果表明,利用硼的吸附数据很好地描述了Freundlich和DR方程。

著录项

  • 来源
    《Desalination and water treatment》 |2011年第3期|p.110-118|共9页
  • 作者单位

    Department of Chemical Engineering, Engineering and Architecture Faculty, Eskisehir Osmangazi University, 26480 Meselik-Eskisehir, Turkey;

    Department of Chemical Engineering, Engineering and Architecture Faculty, Eskisehir Osmangazi University, 26480 Meselik-Eskisehir, Turkey;

    Department of Chemical Engineering, Engineering and Architecture Faculty, Eskisehir Osmangazi University, 26480 Meselik-Eskisehir, Turkey;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    boron; adsorption; kinetic model; activated carbon; olive bagasse;

    机译:硼;吸附动力学模型活性炭;橄榄渣;

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