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Decoloration of Methyl Red by gliding arc discharge

机译:滑动电弧放电使甲基红脱色

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摘要

The degradation of an azo dye, the Methyl Red, has been studied by gliding arc discharge. The main advantage of this process is due to the large production of reactive species, specially the hydroxyl radicals (OH). These radicals are able to oxidize organic pollutants and treat dye wastewater. The coupling of this process with Fenton reagent (Fe~(2+)), with Titanium oxide (TiO_2) and with TiO_2 and Fe~(2+) simultaneously was investigated in order to enhance the decoloration rate. The results show that the decoloration of Methyl Red was more efficient in the presence of Titanium oxide than Fe~(2+). Moreover, the presence of TiO_2 has the same effect as Fe~(2+) and TiO_2 simultaneously. Under optimal condition, the degradation of Methyl Red was around 97.8%. This implies that the majority molecules of Methyl Red are destroyed. In other hand, the hydroxylation reaction of Methyl Red can be treated as a kinetic pseudo-first order.
机译:已经通过滑动电弧放电研究了偶氮染料甲基红的降解。该方法的主要优点是由于大量产生反应性物质,特别是羟基自由基(OH)。这些自由基能够氧化有机污染物并处理染料废水。研究了该方法与Fenton试剂(Fe〜(2+)),二氧化钛(TiO_2)以及TiO_2和Fe〜(2+)的耦合,以提高脱色率。结果表明,在氧化钛存在下,甲基红的脱色比Fe〜(2+)更有效。此外,TiO_2的存在与Fe〜(2+)和TiO_2同时具有相同的作用。在最佳条件下,甲基红的降解率为97.8%左右。这意味着甲基红的大部分分子被破坏了。另一方面,可以将甲基红的羟基化反应视为动力学拟一级。

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  • 来源
    《Desalination and water treatment》 |2011年第3期|p.65-70|共6页
  • 作者单位

    Laboratoire de Chimie Analytique et Electrochimie, Departement de Chimie, Faculte des Sciences de Tunis, Campus Universitaire, 2092 Tunis El Manar, Tunisia;

    Laboratoire de Genie des Procedes Plasma et Traitement de Surface, Ecole Nationale Superieure de Chimie de Paris, 75005 Paris, France;

    Laboratoire de Chimie Analytique et Electrochimie, Departement de Chimie, Faculte des Sciences de Tunis, Campus Universitaire, 2092 Tunis El Manar, Tunisia,Departement de Chimie et de Biologie Appliquees, Institut National des Sciences Appliquees et de Technologie,B.P. 676,1080 Tunis Cedex, Tunisia;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    humid air plasma; gliding arc; methyl red; decoloration;

    机译:湿空气等离子体滑弧甲基红;脱色;

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