The preparation of porous polyamide-imide nanofiber membrane by using electrospinning for MF application

摘要

A membrane material based on polyamide-imide (PAI) has received a great attention lately due to its thermal resistance, outstanding mechanical property, and low thermal expansion coefficient. In this study, we have focused on the preparation of porous PAI nanofiber membranes (PNMs) for water treatments. The preparation of PNMs was completed via the electrospinning method using PAI in a mixed solvent of dimethylacetamide and tetrahydro-furan. The resulting PNMs were then thermally treated to improve mechanical properties. These PAI-based membranes were characterized by scanning electron microscope, tensome-ter (tensile strength and elongation), pore characteristic, contact angle analyzer (contact angle), and dead-end cell device (water flux). We noticed that the pore diameter (1.0-0.3 μm) of PNMs was systematically controlled by simply increasing the number of PNMs layers. As these nanofiber membranes were found to be highly hydrophobic, we also attempted to prepare hydrophilic PNMs with a PAI solution containing 2-4wt.% of diethylene glycol prior to the electrospinng. Based on contact angle tests, these modified PNMs exhibited very hydrophilic characteristics that could be utilized in water-filtration systems.