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Synthesis and characterization of YVO4:Eu3+ nanoparticles: kinetics and isotherm studies for the removal of Cd2+ metal ion

机译:YVO4:Eu3 +纳米粒子的合成与表征:动力学和等温线研究Cd2 +金属离子的去除

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The prepared YVO4:Eu3+ nanoparticle was successfully used for the removal of highly toxic Cd2+ metal ion. Batch experiments were performed as a function of various experimental parameters such as effect of pH (2-8), contact time (5-120min), initial Cd2+ concentration (25-200mgL(-1)), and temperature (25-40 degrees C). The equilibrium was established within 90min where 82% Cd2+ was adsorbed using YVO4:Eu3+ nanoparticles. Kinetic studies showed better applicability for pseudo-second-order model. Langmuir and Freundlich isotherm models were employed for fitting the equilibrium data, and it was found that the Langmuir model fitted the data better than the Freundlich model.
机译:制备的YVO4:Eu3 +纳米粒子已成功用于去除剧毒的Cd2 +金属离子。批处理实验是根据各种实验参数进行的,例如pH值(2-8),接触时间(5-120min),Cd2 +初始浓度(25-200mgL(-1))和温度(25-40度) C)。在90分钟内建立了平衡,其中使用YVO4:Eu3 +纳米颗粒吸附了82%的Cd2 +。动力学研究表明,伪二阶模型具有更好的适用性。用Langmuir和Freundlich等温线模型拟合平衡数据,发现Langmuir模型比Freundlich模型拟合数据更好。

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