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Influence of fluorescent whitening agent on the fluorescent emission of resin composites

机译:荧光增白剂对树脂复合材料荧光发射的影响

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Objectives. The objective of this study was to determine the fluorescent emission of experimental resin composites after addition of a fluorescent whitening agent in varied concentrations. The effects of thermocycling and composition of resin matrix on the fluorescent emission were also determined. Methods. An experimental light curing resin matrix was made by mixing Bis-GMA, UDMA and TEGDMA in the ratio of 1:1:1 by weight, and silane coated glass filler was added in the ratio of 50wt.% of resin composite. A fluorescent whitening agent [FWA, 1,4-double-(benzoxazole-group-2-group)naphthalene] was added with the concentration of 0.01-0.1%. To determine the difference by the resin matrix, two resin composites (60wt.% Bis-GMA or UDMA with 40wt.% TEGDMA) with the same filler content were made, and the FWA was added. Five specimens of 2 mm in thickness were made for each group. Spectral reflectance was measured relative to the illuminant D65 on a reflection spectrophotometer. From the spectral reflectance values, the difference in reflectance (fluorescence spectra) by the inclusion or exclusion of UV component was calculated. After the baseline measurement, thermocycling was performed for 500 and 1000 cycles, and the fluorescent emission was measured again. Results. The concentration of FWA influenced the fluorescent peak heights and areas (p < 0.05), but thermocycling up to 1000 cycles did not influence the values. Fluorescence peak wavelength was not changed by the resin matrix, but peak height and area were influenced by the resin matrix (p < 0.05). Significance. FWA added with the concentrations of 0.01 and 0.05% emitted fluorescence, which was higher than those from commercial resin composites.
机译:目标。这项研究的目的是确定添加各种浓度的荧光增白剂后实验树脂复合材料的荧光发射。还确定了热循环和树脂基质的组成对荧光发射的影响。方法。通过按重量比1:1:1混合Bis-GMA,UDMA和TEGDMA制成实验性光固化树脂基体,并以树脂复合材料的50重量%的比例添加硅烷涂覆的玻璃填料。加入荧光增白剂[FWA,1,4-双-(苯并恶唑-基-2-基)萘],浓度为0.01-0.1%。为了确定树脂基质的差异,制备了两种具有相同填料含量的树脂复合材料(60%(重量)的Bis-GMA或UDMA和40%(重量)的TEGDMA),并添加了FWA。每组制作5个厚度为2mm的样品。在反射分光光度计上相对于光源D65测量光谱反射率。从光谱反射率值计算出由于包含或不包含UV成分而引起的反射率(荧光光谱)的差异。在基线测量之后,进行500和1000个循环的热循环,并再次测量荧光发射。结果。 FWA的浓度影响荧光峰的高度和面积(p <0.05),但热循环最多1000个循环不会影响该值。荧光峰波长不受树脂基质的影响,但峰高和峰面积受树脂基质的影响(p <0.05)。意义。 FWA加入浓度分别为0.01和0.05%时会发出荧光,这要比市售树脂复合材料高。

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