BAPO as an alternative photoinitiator for the radical polymerization of dental resins

摘要

Objectives. This study evaluated the performance of phenylbis (2,4,6-trimethylbenzoyl)-phosphine oxide (BAPO) as an alternative photoinitiator in the polymerization kinetics (PK), flexural strength (σ) and elastic modulus (E) of a model dental resin. Methods. A monomer mixture based on Bis-GMA and TEGDMA was used as model dental resin. Initially a screening was performed to evaluate BAPO concentrations (0.125, 0.25, 0.50, 1, 2, and 4mol%). Photoinitiator systems were formed with the combination of camphorquinone (CQ), ethyl-dimethylamino benzoate (EDAB), diphenyliodonium hexafluorophosphate (DPIHFP), and BAPO. Groups with unitary photoinitiator systems (BAPO and CQ), binary (BAPO + EDAB, BAPO + DPIHFP and CQ+EDAB), ternary (BAPO + CQ+ EDAB, BAPO + CQ+ DPIHFP, BAPO + EDAB + DPIHFP and CQ+ EDAB + DPIHFP) and quaternary (BAPO+ CQ+EDAB + DPIHFP) were formulated for evaluation. Real-time Fourier transform infrared spectroscopy was used to investigate the PK and test mini-bending to evaluate σ and E. Results. When only CQ was used, a slow polymerization reaction was observed and a lower monomer conversion. When only BAPO was used as photoinitiator an increase in the polymerization rate was observed and conversion was higher than CQ+EDAB. The ternary system (BAPO + EDAB + DPIHFP) showed the highest polymerization and conversion rate, in short photo-activation time. Significance. BAPO it is a potential photoinitiator for the photopolymerization of dental materials.