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Preparation and performances of electrically conductive Nb-doped TiO_2 coatings for 316 stainless steel bipolar plates of proton-exchange membrane fuel cells

机译:质子交换膜燃料电池用316不锈钢双极板的Nb掺杂TiO_2导电涂层的制备及性能

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摘要

The dissolution and passivation of the metal bipolar plates is one of the main problems for the commercialization of proton exchange membrane fuel cell (PEMFC). In present study, the adhesive anatase Ti1-xNbxO2 coatings are prepared on the 316 L and their corrosion behavior is also investigated in 0.1 M H2SO4 solution at 80 degrees C. The coatings can increase the corrosion potential of 316 L by more than 200 mY(Ag/Agcl). Thirty-day exposure experiment indicates that the Ti1-xNbxO2 coatings show high stability, and can inhibit effectively the corrosion of the steel. Moreover, a lower interfacial contact resistance is achieved for the Ti0.96Nb0.04O2 coating.
机译:金属双极板的溶解和钝化是质子交换膜燃料电池(PEMFC)商业化的主要问题之一。在本研究中,在316 L上制备了锐钛矿型Ti1-xNbxO2粘合剂涂层,并在80°C的0.1 M H2SO4溶液中研究了它们的腐蚀行为。该涂层可使316 L的腐蚀电位增加200 mY( Ag / Agcl)。 30天的暴露实验表明,Ti1-xNbxO2涂层显示出很高的稳定性,并且可以有效地抑制钢的腐蚀。而且,对于Ti0.96Nb0.04O2涂层实现了较低的界面接触电阻。

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