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Mechanical properties of high strength POM-FRCC and its performance under elevated temperatures

机译:高强度POM-FRCC的力学性能及其在高温下的性能

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摘要

Polyoxymethylene (POM) is one of the polymers with excellent mechanical and durable properties developed in recent years. It has attracted much attention in construction materials thanks to its great concordant compatibility with cement paste in the form of fibre. To evaluate the influence of POM fibres on high strength mortar, compressive, flexural and uni-axial tensile performance of POM fibre-reinforced cementitious composite (POM-FRCC) were experimentally tested in the present study. Results show that 2.0 vol% POM fibres significantly increased the ductility of high strength mortar. Moreover, behaviors of elevated temperatures exposed POM-FRCC were focused in consideration of thermal sensitive nature in polymer fibre. Results indicate that POM fibres help to effectively prevent the spalling of high strength mortar due to their melting around 280 degrees C. Additional hydration products were detected at 200 & ndash;400 degrees C through XRD curves, which might be responsible for the enhancement of compressive strength. Hair-line cracking can be observed under SEM observation beyond 400 degrees C and propagates as the increase of the heating temperature. POM fibres were found shrunk at 200 degrees C and disappeared after 400 degrees C heating, leaving longitudinal channels in the composite. The mechanical properties of composites are greatly reduced beyond 600 degrees C thanks to the synthetic effects of pore coarsening effect, crack propagation and hydrates decomposition.(c) 2021 Elsevier Ltd. All rights reserved.
机译:聚甲醛(POM)是近年来开发出优异的机械和耐用性能的聚合物之一。由于其与纤维形式的水泥浆料很好地相互作用,它引起了建筑材料的许多关注。为了评估POM纤维对高强度砂浆的影响,在本研究中实验测试了POM纤维增强水泥复合材料(POM-FRCC)的压缩,弯曲和单轴拉伸性能。结果表明,2.0 Vol%POM纤维显着增加了高强度砂浆的延展性。此外,考虑到聚合物纤维中的热敏性质,重点是升高温度暴露的温度的行为。结果表明,由于其熔化,POM纤维有助于有效地防止高强度砂浆的熔化左右280℃。在200℃下检测到另外的水合产物; 400℃通过XRD曲线,这可能负责压缩的增强力量。在SEM观察下可以观察到毛发线裂纹,超过400℃,随着加热温度的增加传播。发现POM纤维在200摄氏度下缩小并在加热400摄氏度后消失,在复合材料中留下纵向通道。由于孔粗化效果,裂纹传播和水合物分解的合成效果,复合材料的机械性能大大减少了600℃。(c)2021 Elsevier Ltd.保留所有权利。

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