Preparation of polybenzoxazine-functionalized Fe_3O_4 nanoparticles through in situ Diels-Alder polymerization for high performance magnetic polybenzoxazine/Fe_3O_4 nanocomposites

摘要

Hybrids and nanocomposites of polymer and magnetic Fe_3O_4 nanoparticles have been utilized as magnetically-responsive materials and magnetically-directed nanoparticles. In this work, we prepare polymer-functionalized Fe_3O_4 nanoparticles through in situ Diels-Alder polymerization using maleimide-functionalized Fe_3O_4 nanoparticle as a precursor. Polybenzoxazine-functionalized Fe_3O_4 nanoparticles (MNP-PBz) have been obtained and characterized with Fourier Transform Infrared, X ray photoelectron, and Raman spectroscopies. The high saturation magnetization value of 51.9 emu g~(-1) of the MNP-PBz nanoparticles demonstrates its superparamagnetism. Moreover, MNP-FBz has been utilized as a nanofiller for preparation of cured PBz/MNP-PBz nanocomposites, which contain various MNP-PBz contents of 67, 50,33, and 17 wt.%. The sample of PBz/MNP-PBz-67 shows a storage modulus of 8.0 GPa, a saturation magnetization value of 37.6 emu g~(-1) and a glass transition temperature above 380 ℃. As a result, the PBz/MNP-PBz nanocomposites could be classified as magnetically-responsive high performance materials.