The effect of milled carbon fibre filler on electrical conductivity in highly conductive polymer composites

摘要

Carbon based composites are extensively used in applications such as in polymer composite bipolar plates. This study was conducted to investigate the potential of both the use of milled carbon fibre as a conductive filler in a composite and the adaption of the General Effective Media (GEM) model to predict the electrical conductivity of the polymer composite produced. Polymer composites with various loading concentrations of the conductive filler with epoxy (EP) resin were developed using the compression moulding technique. Incorporating carbon nano tube (CNT) and carbon black (CB) as secondary fillers on carbon fibre (CF) reinforces epoxy composites aided in increasing the electrical conductivity of the composites. The addition of small amounts of CNT and CB as secondary fillers in hybrid systems increased the through-plane conductivity to 40.3 S/cm and 19.9 S/cm, respectively. The high aspect ratio and small size of the CNT filled the gaps between CF as primary filler so that there was a more conductive path. These phenomena increased the electrical conductivity of the CNT/CF/EP composites to a level higher than that of the CB/CF/EP composites. The flexural strength of CF/EP also improved from 64.37 MPa to 80 MPa and 70 MPa by adding CNT and CB, respectively. The dispersion and conductive paths mechanism were also investigated using scanning electron microscopy (SEM). (C) 2016 Published by Elsevier Ltd.