Thermal decomposition of energetic materials 82. Correlations of gaseous products with the composition of Aliphatic nitrate esters

摘要

T-Jump/FTIR and T-jump/Raman spectroscopies were used to analyze the gaseous products from six nitrate esters which were rapidly heated(2000°C/s nominal)to set temperatures in the 250 to 500 deg. C range while maintaining a pressure of 5 atm Ar. The compounds studied were nitroglycerin(NG), pentaerythritol tetranitrate(PETN), butanetriol trinitrate(BTTN), trimethanolethane trinitrate(TMETN), triethyleneglycol dinitrate(TEGDN), and bis(nitratomethyl)oxetane(BNMO). The atom balances were determined using all of the gaseous decomposition products based on quantitation by multivariate regression methods.