Thermodynamic study on elimination of platinum inclusions in phosphate laser glasses for inertial confinement fusion apppications

摘要

A new method to calculate the formation enthalpies and free energies of compounds based on standard electromotive force of cationφ~0, and free energies of formation, ΔG~0_298, or formation enthalpies, ΔH~0_298, of chloride was proposed. A linear relationship betweenφ~0 and ΔG~0_298,Φ~0 andΔH~0_298 andΔG~0_298ΔH~0_298 was found respectively. The parameters used for Thermodynaimc calculation were calculated.