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Properties of dilute solutions of hydrophobicaly modified poly(4-vinyl pyridine) (polysoaps)

机译:疏水改性的聚(4-乙烯基吡啶)(聚皂)的稀溶液的性质

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摘要

Hydrophobically modified poly (4-vinyl pyridines) by alkyl bromides are kinds of polysoap similar to the surfactant. Properties of dilute solutions were studied through the viscosity measurements in pure water and NaCl solutions. In aqueous solu- tions of polysoaps hudrophobic interaction can be attributed to aggregation of hydrohobic groups of the olysoap main chains. The hydrophobic groups of polysoap can aggregate to form hydrophobic microdomains (micelles) I aqueous solution. This is a compact confor- mation. The formation of such microdomains is a process of dynamic equilibrium.
机译:通过烷基溴进行疏水改性的聚(4-乙烯基吡啶)是类似于表面活性剂的多种聚皂。通过在纯水和NaCl溶液中的粘度测量来研究稀溶液的性质。在多皂的水溶液中,多疏水相互作用可归因于多皂主链的疏水基团的聚集。聚皂的疏水基团可聚集形成疏水微区(胶束)I水溶液。这是一个紧凑的构造。这种微区的形成是动态平衡的过程。

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