A study on some macrocyclic bicopper(Ⅱ) complexes as the model compounds of superoxide dismutase

QIAN Wen; MEI Guang-Quan; LUO Qin-Hui

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A study on some macrocyclic bicopper(Ⅱ) complexes as the model compounds of superoxide dismutase

机译：大环双铜（Ⅱ）配合物作为超氧化物歧化酶模型化合物的研究

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摘要

24-Membered macrocyclic bicopper(Ⅱ) complexes wth bridging ligand imidzaolate, SCN~-, N_3~- and H_2O respectively were synthesized by condensation of diacetylpyridine with 3-oxapentane-1,5-diamine. As the model compounds of superoxide dismutase (SOD), the relationship between their SOD activities and properties of bridging ligands and redox potentials of copper(Ⅱ) were studied.

机译：通过二乙酰吡啶与3-氧杂戊烷-1,5-二胺的缩合反应合成了具有桥联配体咪唑酸酯，SCN〜-，N_3-〜和H_2O的24元大环双铜（Ⅱ）配合物。研究了超氧化物歧化酶（SOD）的模型化合物，其超氧化物歧化酶（SOD）活性和桥联配体的性质与铜的氧化还原电位之间的关系。

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来源
《Chinese Journal of Chemistry》 |1996年第2期|p.114-122|共9页
作者
QIAN Wen; MEI Guang-Quan; LUO Qin-Hui;
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作者单位

State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, Jiangsu 210093, China;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
macrocyclic complex; bicopper(Ⅱ); superoxide dismutase (SOD); model compound; activity; redox potential;

机译：大环配合物;铜铜（Ⅱ）;超氧化物歧化酶（SOD）;模型化合物;活性;氧化还原电势;

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1. A study on some macrocyclic bicopper(Ⅱ) complexes as the model compounds of superoxide dismutase [J] . 中国化学：英文版 . 1996,第002期

机译：一些宏环双泊（Ⅱ）复合物作为超氧化物歧化酶模型化合物的研究
2. Iron(III) complexes as superoxide dismutase mimics: Synthesis, characterization, crystal structure, and superoxide dismutase (SOD) activity of iron(III) complexes containing pentaaza macrocyclic ligands [J] . Zhang D., Lennon PL., Weiss RH., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第5期

机译：铁（III）配合物作为超氧化物歧化酶的模拟物：含有五氮杂大环配体的铁（III）配合物的合成，表征，晶体结构和超氧化物歧化酶（SOD）活性
3. Imidazolate-bridged dicopper(II) and copper(II)-zinc(II) complexes of macrocyclic ligand with methylimidazol pendants: Model study of copper II)-zinc(II) superoxide dismutase [J] . Yuan Q, Cai K, Qi ZP, Journal of Inorganic Biochemistry: An Interdisciplinary Journal . 2009,第8期

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4. UV resonance Raman studies on metal-bound histidine model compounds of Cu, Zn superoxide dismutase [C] . Qiang Wu, Andrzej A. Jarzecki, Gurusamy Balakrishnan, International Conference on Raman Spectroscopy . 2000

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5. De novo design of human copper/zinc superoxide dismutase ligands in relation to amyotrophic lateral sclerosis/QSAR studies of cyclazocine series compounds [D] . Zhang, Hongmei Michelle 2007

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6. Bisamidate and Mixed Amine/Amidate NiN2S2 Complexes as Models for Nickel-Containing Acetyl Coenzyme A Synthase and Superoxide Dismutase: An Experimental and Computational Study [O] . Vaidyanathan Mathrubootham, Jason Thomas, Richard Staples, -1

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8. Compounds Inhibiting the Aggregation of Superoxide Dismutase-1. [R] . Lansbury, P., Choi, A., Ray, S., 2006

机译：抑制超氧化物歧化酶-1聚集的化合物。

A study on some macrocyclic bicopper(Ⅱ) complexes as the model compounds of superoxide dismutase

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