Oxidation of flumequine in aqueous solution by UV-activated peroxymonosulfate: Kinetics, water matrix effects, degradation products and reaction pathways

摘要

The degradation of flumequine (FLU) in aqueous solution by ultraviolet (UV)-activated peroxymonosulfate (PMS) was investigated in this work. Under the conditions of [PMS](0):[FLU](0) =1:1, T = 25 +/- 2 degrees C, pH = 7.0 +/- 0.1, nearly complete removal of FLU was achieved after 60 min. The effects of various operating parameters, including oxidant doses, pH, the presence of typical ions (NH4+, Mg2+, Fe3+, Cl-, No-3(-), HCO3-) and humic acid were evaluated. It was found that the pseudo-first-order rate constants of FLU degradation increased with increasing PMS dosage and decreasing solution pH. The presence of Mg2+ could accelerate FLU removal, while Fe3+, HCO3-, NO3- and HA inhibited the reaction. Moreover, the degradation of FLU in different water matrices were also explored, and the removal followed the order of Tap water Ultrapure water River water Secondary clarifier effluent. According to the control and radical quenching experiment results, direct photolysis and reactive radicals (SO4 center dot(-) and HO center dot) contributed mainly to FLU degradation in the UV/PMS system. Initial FLU molecule underwent reactions such as hydroxylation, hydroxyl substitution, demethylation, decarboxylation/decarbonylation and ring opening, leading to the formation of nineteen oxidation products. The effective degradation by UV/PMS suggests a feasible technology for treating FLU in waters and wastewaters. (C) 2019 Elsevier Ltd. All rights reserved.