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外文期刊>Chemistry - A European Journal
>Polar 2D Sheet versus Nonpolar 1D Helix Metallosupramolecular Architectures Based on M6M′8 (M=PdII, NiII; M′=CuI, AgI) Cage Clusters with D
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Polar 2D Sheet versus Nonpolar 1D Helix Metallosupramolecular Architectures Based on M6M′8 (M=PdII, NiII; M′=CuI, AgI) Cage Clusters with D
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机译:基于M 6 sub> M′ 8 sub>(M = Pd II sup>,Ni II sup>; M'= Cu I sup>,Ag I sup>)D笼子簇
To coil or not to coil: Chiral S-bridged 14-nuclear clusters with 12 free carboxylate groups, [M6M′8(D-pen)12Cl]5− (M=PdII, NiII; M′=CuI, AgI; D-pen=D-penicillaminate; see scheme), prepared from [M(D-pen)2]2− and M′Cl, were organized into heterotrimetallic supramolecular structures in combination with La3+.
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机译:收卷或不收卷:具有12个游离羧酸酯基的手性S桥联14核簇,[M 6 sub> M' 8 sub>(D-pen) 12 sub> Cl] 5 − sup>(M = Pd II sup>,Ni II sup>; M'= Cu I sup> ,Ag I sup>; D-pen = D-penicillaminate;请参见方案),由[M(D-pen) 2 sub>] 2- sup>制备La和M'Cl与La 3 + sup>结合组成杂三金属超分子结构。
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