A Novel Soluble InI Precursor for P<sub>n</sub> Ligand Coordination Chemistry

Stefan Welsch; Michael Bodensteiner; Dr. Michal Dušek; Dr. Marek Sierka; Prof. Dr. Manfred Scheer

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A Novel Soluble InI Precursor for P_n Ligand Coordination Chemistry

机译：P _{n 配体配位化学的新型可溶In I 前体}

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摘要

A new soluble In+source containing the very weakly coordinating anion [Al{OC(CF₃)₃}₄]− was developed. In reaction with a P₂ ligand complex an unprecedented tetracationic aggregate is formed featuring a short InIn distance (see picture). Polymeric strands arising from a reaction with a cyclo-P₃ ligand complex exhibit a novel coordination mode for P₃ units.

机译：一种新的可溶性In + 源，其中包含非常弱配位的阴离子[Al {OC（CF _{3 ）_{3 } _{4 ] -被开发。与P _{2 配体络合物反应，形成了空前的InIn距离较短的四阳离子聚集体（见图）。与环-P _{3 配体复合物反应产生的聚合物链对P _{3 单元具有新颖的配位方式。}}}}}}

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来源
《Chemistry - A European Journal》 |2010年第44期|p.13041-13045|共5页
作者
Stefan Welsch; Michael Bodensteiner; Dr. Michal Dušek; Dr. Marek Sierka; Prof. Dr. Manfred Scheer;
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作者单位

Institut fü

r Anorganische Chemie, Universitt Regensburg, 93040 Regensburg (Germany), Fax: (+49)

941-943-4439;

Institute of Physics, Academy of Science of the Czech Republic, 16253 Praha 6 (Czeck Republic);

Institut fü

r Chemie, Humboldt-Universitt zu Berlin, 10099 Berlin (Germany);

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原文格式 PDF
正文语种 eng
中图分类
关键词
coordination polymers; Group 13 elements; indium; phosphorus; weakly coordinating anions;

机译：配位聚合物;13族元素;铟;磷;弱配位阴离子;

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A Novel Soluble InI Precursor for Pn Ligand Coordination Chemistry

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A Novel Soluble InI Precursor for P_n Ligand Coordination Chemistry