...
首页> 外文期刊>Chemistry - A European Journal >Oxidative Perhydroxylation of [closo-B12H12]2− to the Stable Inorganic Cluster Redox System [B12(OH)12]2−/.−: Experiment and Theory†
【24h】

Oxidative Perhydroxylation of [closo-B12H12]2− to the Stable Inorganic Cluster Redox System [B12(OH)12]2−/.−: Experiment and Theory†

机译:[closo-B 12 H 12 ] 2-的氧化过羟基化反应对稳定的无机簇氧化还原系统[B 12 >(OH) 12 ] 2-/ .- :实验与理论†

获取原文
获取原文并翻译 | 示例
           

摘要

It′s radical: A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster [closo-B12H12]2− not only to [closo-B12(OH)12]2− but also, at less-elevated temperatures, to the new [hypocloso-B12(OH)12].− radical anion (see figure). Both approximately icosahedral closo and hypocloso cluster ions were structurally characterized as the cesium salts and their properties were assessed experimentally and theoretically.
机译:它是激进的:令人惊讶的简单反应将通常呈惰性的氢硼酸盐原型簇[closo-B 12 H 12 ] 2-转化为[closo-B 12 (OH) 12 ] 2-,但在较低的温度下也可以生成新的[hypocloso-B < sub> 12 (OH) 12 ] .− 自由基阴离子(见图)。近似二十面体的closo和次氯酸簇离子都在结构上被表征为铯盐,并通过实验和理论评估了它们的性质。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号