Single-Side Organically Functionalized Anderson-Type Polyoxometalates

摘要

An unprecedented single-side trisalkoxo-substituted Anderson-type polyoxometalate (POM) was synthesized (see scheme). As confirmed by single-crystal X-ray diffraction and IR analyses, the single-side-functionalized Anderson-type POM forms interesting supramolecular assemblies, including dimers and 1D chains.