Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex

摘要

A cobalt complex [{Co(dpqa)}_2(dhbq)](PF_6)_3 (1(PF_6)_3, dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone, dpqa = di(2-pyridyl-methyl)-N-(quinolin-2-ylmethyl)amine) was prepared and studied by X-ray diffraction, electrochemistry, ESR, thermally and pho