Eight coordination with bis(bidentate) bridging ligands: zeolitic topology versus square grid networks

摘要

The assembly of the asymmetric bis(bidentate) 2-pyrimidinecar-boxylate ligand with Cd~Ⅱ produces a metal-organic framework with the RHO zeolitic topology, while 5-(2'-pyrimidyl)tetra-zolate with Cd~Ⅱ leads to square grid networks.