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Efficient aqueous hydrogenation of biomass platform molecules using supported metal nanoparticles on Starbons~®

机译:在Starbons〜®上使用负载的金属纳米颗粒对生物质平台分子进行有效的水氢化

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摘要

An efficient protocol for the hydrogenation of platform molecules (e.g. succinic acid) in aqueous environments using supported metal nanoparticles on polysaccharide derived mesoporous carbonaceous materials is reported for the first time.rnThe drive towards greener process chemistry has resulted in various research reports of the partial or even complete replacement of organic solvents with water in a few organic reactions. However, these tend to involve unusual circumstances and/or conditions (e.g. aggregation of hydrophobic compounds, use of supercritical conditions, presence of surfactants, etc.) and remain the exception.
机译:首次报道了在多糖衍生的介孔碳质材料上使用负载的金属纳米粒子在水性环境中氢化平台分子(例如琥珀酸)的有效方法。甚至在一些有机反应中完全用水代替有机溶剂。然而,这些倾向于涉及不寻常的情况和/或条件(例如疏水性化合物的聚集,超临界条件的使用,表面活性剂的存在等),并且仍然是例外。

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  • 来源
    《Chemical Communications》 |2009年第35期|5305-5307|共3页
  • 作者单位

    Green Chemistry Centre of Excellence, The University of York, UK YO10 5DD;

    Green Chemistry Centre of Excellence, The University of York, UK YO10 5DD;

    Nanocentre, Department of Chemistry, The University of York, UK YO10 5DD;

    Nanocentre, Department of Chemistry, The University of York, UK YO10 5DD Department of Physics, The University of York, UK YO10 5BR;

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