Remarkable regioselectivity in the preparation of the first heterotrimetallic Mo ≡ W...Cr chain

Michael Nippe; George H. Timmer; John F. Berry

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Remarkable regioselectivity in the preparation of the first heterotrimetallic Mo ≡ W...Cr chain

机译：在制备第一个杂三金属Mo≡W ... Cr链时具有显着的区域选择性

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Addition of CrCl_2 to the dinuclear synthon MoW(dpa)_4 yields a regioselectively formed heterotrimetallic Mo≡W...Cr chain; computational studies suggest that the polarization of the Mo ≡ W quadruple bond partially accounts for this unexpected selectivity.

机译：在双核合成子MoW（dpa）_4中添加CrCl_2会产生区域选择性形成的异三金属Mo≡W... Cr链；计算研究表明，Mo≡W四键的极化部分解释了这种意外的选择性。

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《Chemical Communications》 |2009年第29期|357-359|共3页
作者
Michael Nippe; George H. Timmer; John F. Berry;
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Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, WI 53706, USA;

Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, WI 53706, USA;

Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, WI 53706, USA;

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入库时间 2022-08-17 13:25:45

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Remarkable regioselectivity in the preparation of the first heterotrimetallic Mo ≡ W...Cr chain

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