Facile synthesis of hypersilylated aromatic compounds by palladium-mediated arylation reaction

摘要

The treatment of aryl iodides with tris(trimethylsilyl)silane in the presence of Pd(P(tBu)_3)_2 and the Hiinig base leads to the formation of hypersilylated aromatic products in good to excellent yields without cleavage of weak Si-Si bonds under mild conditions.