Continuous modulation of electronic structure of stable thiolate-protected Au_(25) cluster by Ag doping

Yuichi Negishi; rnTakeyuki Iwai; rnMao Ide

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Continuous modulation of electronic structure of stable thiolate-protected Au_(25) cluster by Ag doping

机译：Ag掺杂对稳定硫醇盐保护的Au_（25）团簇电子结构的连续调节

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The effect of Ag doping on the electronic structure of a stable thiolate-protected Au_(25) cluster (Au_(25)(SR)_(18)) was studied by measuring the optical spectra of Au_(25_n)Ag_n(SC_(12)H_(25))_(18) (n = 0-11) and the results reveal that the electronic structure of Au_(25)(SC_(12)H_(25))_(18) is sensitive to Ag doping and is continuously modulated by incorporation of Ag atoms.

机译：通过测量Au_（25_n）Ag_n（SC_（12）的光谱，研究了Ag掺杂对稳定的硫醇盐保护的Au_（25）团簇（Au_（25）（SR）_（18））的电子结构的影响。）H_（25））_（18）（n = 0-11），结果表明Au_（25）（SC_（12）H_（25））_（18）的电子结构对Ag掺杂和通过掺入Ag原子来连续地调节。

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来源
《Chemical Communications》 |2010年第26期|P.4713-4715|共3页
作者
Yuichi Negishi; rnTakeyuki Iwai; rnMao Ide;
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作者单位

Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan;

rnDepartment of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan;

rnDepartment of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan;

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1. Size and Structure Dependence of Electronic States in Thiolate-Protected Gold Nanoclusters of Au_(25)(SR)_(18), Au_(38)(SR)_(24), and Au_(144)(SR)_(60) [J] . Tsutomu Ohta, Masahiro Shibuta, Hironori Tsunoyama The journal of physical chemistry, C. Nanomaterials and interfaces . 2013,第7期

机译：受Au_（25）（SR）_（18），Au_（38）（SR）_（24）和Au_（144）（SR）_（60）硫醇盐保护的金纳米团簇中电子态的尺寸和结构依赖性
2. Size and Structure Dependence of Electronic States in Thiolate-Protected Gold Nanoclusters of Au_(25)(SR)_(18), Au_(38)(SR)_(24), and Au_(144)(SR)_(60) [J] . Tsutomu Ohta, Masahiro Shibuta, Hironori Tsunoyama The journal of physical chemistry, C. Nanomaterials and interfaces . 2013,第7期

机译：受Au_（25）（SR）_（18），Au_（38）（SR）_（24）和Au_（144）（SR）_（60）硫醇盐保护的金纳米团簇中电子态的尺寸和结构依赖性
3. Electronic structure and optical properties of the thiolate-protected Au_(28)(SMe)_(20) cluster [J] . Knoppe S., Malola S., Lehtovaara L., The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2013,第40期

机译：硫醇盐保护的Au_（28）（SMe）_（20）团簇的电子结构和光学性质
4. EBIC and CL imaging of self-organised quantum dot clusters and wetting layers in modulation-doped structures [C] . C E Norman, A J Shields, R A Hogg, Microscopy of semiconducting materials 1999 . 1999

机译：调制掺杂结构中自组织量子点簇和润湿层的EBIC和CL成像
5. Geometry and electronic structure of doped clusters via the coalescence Kick method. [D] . Averkiev, Boris. 2009

机译：通过聚结踢方法对掺杂团簇的几何结构和电子结构进行研究。
6. Probing the structure and electronic properties of beryllium doped boron clusters: A planar BeB16− cluster motif for metallo-borophene [O] . Dongliang Kang, Weiguo Sun, Hongxiao Shi, -1

机译：探究铍掺杂硼团簇的结构和电子性质：金属硼烷的平面BeB16-团簇基序
7. Electronic Structure and Bonding of Icosahedral Core-Shell Gold-Silver Nanoalloy Clusters Au_(144-x)Ag_x(SR)_60 [O] . Malola, Sami, Häkkinen, Hannu 2011

机译：二十面体核壳金银的电子结构与键合 Nanoalloy Clusters au_（144-x）ag_x（sR）_60

Continuous modulation of electronic structure of stable thiolate-protected Au_(25) cluster by Ag doping

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