Multifunctional periodic mesoporous organosilicas with bridging groups formed via dynamic covalent chemistry

Eun-Bum Cho; Oc Hee Han; Sunha Kim; Dukjoon Kim; Mietek Jaroniec

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Multifunctional periodic mesoporous organosilicas with bridging groups formed via dynamic covalent chemistry

机译：通过动态共价化学形成具有桥联基团的多功能周期性介孔有机硅

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摘要

Imine-containing bridging groups were formed during self-assembly of periodic mesoporous organosilicas by in situ dynamic covalent chemistry of aldehyde and amine groups in the presence of poly(ethylene oxide)-poly(DL-lactic acid-co-glycolic acid)-poly(ethylene oxide) block copolymer in acidic aqueous solutions.

机译：在聚（环氧乙烷）-聚（DL-乳酸-共乙醇酸）-聚存在的情况下，通过醛和胺基团的原位动态共价化学反应，在周期性介孔有机硅自组装过程中形成了含亚胺的桥接基团。（环氧乙烷）嵌段共聚物在酸性水溶液中。

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《Chemical Communications》 |2010年第25期|P.4568-4570|共3页
作者
Eun-Bum Cho; Oc Hee Han; Sunha Kim; Dukjoon Kim; Mietek Jaroniec;
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作者单位

Department of Chemistry, Kent State University, Kent, Ohio 44242, USA;

rnAnalysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu 702-701, Korea;

rnAnalysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu 702-701, Korea;

Department of Chemical Engineering, Polymer Technology Institute, Sungkyunkwan University, Suwon, Gyeonggi-do 440-746, Korea;

rnDepartment of Chemistry, Kent State University, Kent, Ohio 44242, USA;

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3. Functionalized MoS2 nanosheet-capped periodic mesoporous organosilicas as a multifunctional platform for synergistic targeted chemo-photothermal therapy [J] . Wu Jianrong, Bremner David H., Niu Shiwei, Chemical engineering journal . 2018,第期

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4. Recent developments in the synthesis and chemistry of periodic mesoporous organosilicas [C] . Tewodros Asefa, Geoffrey A. Ozin, Hiltrud Grondey, 3rd International Symposium on Nanoporous Materials, Jun 12-15, 2002, Ottawa, Ontario, Canada . 2002

机译：周期性介孔有机硅的合成与化学研究进展
5. High Performance Computational Chemistry: Bridging Quantum Mechanics, Molecular Dynamics, and Coarse-Grained Models. [D] . Ozog, David M. 2017

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6. Fabrication of multifunctional triple-responsive platform based on CuS-capped periodic mesoporous organosilica nanoparticles for chemo-photothermal therapy [O] . Xiangyang Cheng, Dejian Li, Aiqi Lin, 2018

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8. Sunlight-Catalyzed Conversion of Cyclic Organics with Novel Mesoporous Organosilicas [R] . Johnson-White, B., Zeinali, M., Malanoski, A. P., 2006

机译：新型催化转化环状有机物与新型介孔有机硅

Multifunctional periodic mesoporous organosilicas with bridging groups formed via dynamic covalent chemistry

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