Reversible luminescent reaction of amines with copper(I) cyanide

Amanda N. Ley; Lars E. Dunaway; Timothy P. Brewster; Matthew D. Dembo; T. David Harris; Francois Baril-Robert; Xiaobo Li; Howard H. Patterson; Robert D. Pike

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Reversible luminescent reaction of amines with copper(I) cyanide

机译：胺与氰化铜（I）的可逆发光反应

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Copper(I) cyanide exposed to various liquid or vapor-phase amines (L) at ambient temperature produces a variety of visible photoluminescence colors via reversible formation of amine adducts. The adducts show phase matches to authentic (CuCN)L_n, n = 0.75-2.0, produced by heating CuCN with liquid amine.

机译：在环境温度下暴露于各种液相或气相胺（L）的氰化铜（I）通过可逆形成胺加合物而产生各种可见的光致发光颜色。加合物显示出与真实的（CuCN）L_n相匹配，n = 0.75-2.0，这是通过将CuCN与液体胺加热而产生的。

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《Chemical Communications》 |2010年第25期|P.4565-4567|共3页
作者
Amanda N. Ley; Lars E. Dunaway; Timothy P. Brewster; Matthew D. Dembo; T. David Harris; Francois Baril-Robert; Xiaobo Li; Howard H. Patterson; Robert D. Pike;
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Department of Chemistry, College of William and Mary, Williamsburg, VA 23187-8795, USA;

rnDepartment of Chemistry, College of William and Mary, Williamsburg, VA 23187-8795, USA;

rnDepartment of Chemistry, College of William and Mary, Williamsburg, VA 23187-8795, USA;

rnDepartment of Chemistry, College of William and Mary, Williamsburg, VA 23187-8795, USA;

rnDepartment of Chemistry, University of California, Berkeley, CA 94720-1460, USA;

rnDepartment of Chemistry, University of Maine, Orono, ME 04469-5706, USA;

rnDepartment of Chemistry, University of Maine, Orono, ME 04469-5706, USA;

rnDepartment of Chemistry, University of Maine, Orono, ME 04469-5706, USA;

rnDepartment of Chemistry, College of William and Mary, Williamsburg, VA 23187-8795, USA;

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入库时间 2022-08-17 13:23:51

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Reversible luminescent reaction of amines with copper(I) cyanide

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