A highly-connected acentric organic-inorganic hybrid material with unique 3D inorganic and 3D organic connectivity

摘要

An unprecedented organic-inorganic hybrid material with 3D inorganic and 3D organic connectivity has been constructed based on Cd(n) and tetrazolate-5-carboxylate, which shows a highly connected trinodal (4,8,16-c) topological net and SHG activity.rnOrganic-inorganic hybrid materials, in which both organic and inorganic structural elements co-exist within a single phase, have been extensively studied over the past two decades as they endow both advantages of inorganic and organic materials.