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首页> 外文期刊>Chemical Communications >Self-assembly from metal-organic vesicles to globular networks: metallogel-mediated phenylation of indole with phenyl boronic acid
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Self-assembly from metal-organic vesicles to globular networks: metallogel-mediated phenylation of indole with phenyl boronic acid

机译：从金属有机小泡到球状网络的自组装：吲哚与苯硼酸的金属链介导的苯基化

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摘要

Self-assembly of the conformationally flexible bismethylimidazolyl ligands with Pd(OAc)_2 is described. Depending on whether the ligands provide the hydrogen bonding donor, a switching of metal-organic vesicles to globular networks gelating solvents is achieved. The metallogels exhibit catalytic activity for the cross-coupling of indole with phenyl boronic acid.
机译：描述了构象柔性的双甲基咪唑基配体与Pd（OAc）_2的自组装。取决于配体是否提供氢键供体，实现了金属有机囊泡向球形网络胶凝溶剂的转换。这些金属化合物显示出吲哚与苯基硼酸的交叉偶联的催化活性。

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  • 来源
    《Chemical Communications》 |2010年第22期|P.3938-3940|共3页
  • 作者

    Li Yang; Liang Luo; Shuai Zhang; Xiaoyu Su; Jingbo Lan; Chi-Tien Chen; Jingsong You;

  • 作者单位

    Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Hospital,Sichuan University, Chengdu 610064, People's Republic of China;

    Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Hospital,Sichuan University, Chengdu 610064, People's Republic of China;

    Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Hospital,Sichuan University, Chengdu 610064, People's Republic of China;

    Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Hospital,Sichuan University, Chengdu 610064, People's Republic of China;

    Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Hospital,Sichuan University, Chengdu 610064, People's Republic of China;

    Department of Chemistry, National Chung Hsing University,Taichung 402, Taiwan;

    Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Hospital,Sichuan University, Chengdu 610064, People's Republic of China;

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  • 入库时间 2022-08-17 13:23:48

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