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Chirality and magnetism of an open-framework cobalt phosphite containing helical channels from achiral materials

机译：具有非手性材料的螺旋结构的开放骨架亚磷酸钴的手性和磁性

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摘要

A new chiral open-framework cobalt phosphite [C_6N_2H_(14)]-[Co(HPO_3)_2] (1) with helical channels has been synthesized under solvothermal conditions in the presence of achiral organic amine. The circular dichroism (CD) spectrum indicates that the bulk crystals have optical activity. Magnetic measurements reveal that 1 is a weak ferromagnet.
机译：在非手性有机胺的存在下，在溶剂热条件下合成了具有螺旋通道的手性开放骨架亚磷酸钴[C_6N_2H_（14）]-[Co（HPO_3）_2]（1）。圆二色性（CD）光谱表明块状晶体具有光学活性。磁性测量表明1是弱铁磁体。

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  • 来源
    《Chemical Communications》 |2010年第15期|p.2614-2616|共3页
  • 作者

    Xianchun Liu; Yan Xing; Xinlong Wang; Hongbin Xu; Xizheng Liu; Kuizhan Shao; Zhongmin Su;

  • 作者单位

    Department of Chemistry, Northeast Normal University,Changchun, 130024, P. R. China;

    Department of Chemistry, Northeast Normal University,Changchun, 130024, P. R. China;

    Department of Chemistry, Northeast Normal University,Changchun, 130024, P. R. China;

    China Science and Technology Exchange Center, Ministry of Science and Technology, Beijing, 100045, P. R. China;

    Department of Chemistry, Northeast Normal University,Changchun, 130024, P. R. China;

    Department of Chemistry, Northeast Normal University,Changchun, 130024, P. R. China;

    Department of Chemistry, Northeast Normal University,Changchun, 130024, P. R. China;

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