Pressure-induced Jahn-Teller switching in a Mn_(12) nanomagnet

Pascal Parois; Stephen A. Moggach; Javier Sanchez-Benitez; Konstantin V. Kamenev; Alistair R. Lennie; John E. Warren; Euan K. Brechin; Simon Parsons; Mark Murrie

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Pressure-induced Jahn-Teller switching in a Mn_(12) nanomagnet

机译：Mn_（12）纳米磁铁中的压力感应Jahn-Teller切换

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摘要

Pressure-induced switching of a fast-relaxing single-molecule magnet to a slow-relaxing isomer is observed for the first time by using a combination of high pressure single-crystal X-ray diffraction and high pressure magnetic measurements.

机译：通过结合使用高压单晶X射线衍射和高压磁测量，首次观察到压力诱导的快弛豫单分子磁体向慢弛豫异构体的转换。

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《Chemical Communications》 |2010年第11期|1881-1883|共3页
作者
Pascal Parois; Stephen A. Moggach; Javier Sanchez-Benitez; Konstantin V. Kamenev; Alistair R. Lennie; John E. Warren; Euan K. Brechin; Simon Parsons; Mark Murrie;
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WestCHEM, Department of Chemistry, University of Glasgow,University Avenue, Glasgow, UK G12 8QQ;

School of Chemistry and Centre for Science at Extreme Conditions,University of Edinburgh, West Mains Road, Edinburgh,UK EH9 3JJ;

School of Chemistry and Centre for Science at Extreme Conditions,University of Edinburgh, West Mains Road, Edinburgh,UK EH9 3JJ;

School of Chemistry and Centre for Science at Extreme Conditions,University of Edinburgh, West Mains Road, Edinburgh,UK EH9 3JJ;

STFC Daresbury Laboratory, Warrington, Cheshire, UK W A4 4AD;

STFC Daresbury Laboratory, Warrington, Cheshire, UK W A4 4AD;

School of Chemistry and Centre for Science at Extreme Conditions,University of Edinburgh, West Mains Road, Edinburgh,UK EH9 3JJ;

School of Chemistry and Centre for Science at Extreme Conditions,University of Edinburgh, West Mains Road, Edinburgh,UK EH9 3JJ;

WestCHEM, Department of Chemistry, University of Glasgow,University Avenue, Glasgow, UK G12 8QQ;

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入库时间 2022-08-17 13:23:33

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1. Alignment of magnetic anisotropy axes in crystals of Mn_(12) acetate and Mn_(12)-tBuAc molecular nanomagnets: Angle-dependent ac susceptibility study [J] . E. Burzuri, Ch. Carbonera, F. Luis, Physical review . 2009,第22期

机译：乙酸Mn_（12）和Mn_（12）-tBuAc分子纳米磁体晶体中磁各向异性轴的对准：角依赖的磁化率研究
2. Conductive Hybrid Films of Polyarylamine Electrochemically Oxidized with the Molecular Nanomagnet[Mn_(12)O_(12)(H_2O)_4-(C_6F_5COO)_(16)] [J] . Henk J. Bolink, Eugenio Coronado, Alicia Forment-Aliaga, Advanced Materials . 2005,第8期

机译：分子纳米磁体电化学氧化的聚芳胺导电杂化膜[Mn_（12）O_（12）（H_2O）_4-（C_6F_5COO）_（16）]
3. Electronic and geometrical structure and magnetic ordering in passivated Mn_(12)O_(12)-acetate nanomagnets [J] . M. R. Pederson, S. N. Khanna Chemical Physics Letters . 1999,第3a4期

机译：钝化Mn_（12）O_（12）-乙酸盐纳米磁体中的电子和几何结构以及磁排序
4. ATOMIC, ELECTRONIC AND VIBRATIONAL STRUCTURE AND MAGNETIC ANISOTROPY OF MN_(12)O_(12)-ACETATE NANOMAGNETS [C] . M. R. PEDERSON, JENS KORTUS, S. N. KHANNA International symposium on cluster and nanostructure interfaces . 2000

机译：原子，电子和振动结构和Mn_（12）O_（12）的磁各向异性 - 乙酸纳米磁镜
5. Design, fault studies, and performance analysis for nanomagnet logic PLAs and other nanomagnet logic architectures. [D] . Crocker, Michael S. 2011

机译：纳米磁铁逻辑PLA和其他纳米磁铁逻辑体系结构的设计，故障研究和性能分析。
6. Switching of perpendicularly polarized nanomagnets with spin orbit torque without an external magnetic field by engineering a tilted anisotropy [O] . Long You, OukJae Lee, Debanjan Bhowmik, 2015

机译：通过设计倾斜各向异性在没有外部磁场的情况下用自旋轨道转矩切换垂直极化纳米磁体
7. Pressure-induced Jahn–Teller switching in a Mn12 nanomagnet [O] . Pascal Parois, Stephen A. Moggach, Javier Sanchez-Benitez, 2010

机译：压力诱导的jahn-talker切换在Mn12纳米磁体中
8. Final Report, Hydrogen Trapping Through Designer Hydrogen Spillover Molecules with Reversible Temperature and Pressure-Induced Switching. [R] . Lueking, A. D., Li, J., Wang, C. Y., 2014

机译：最终报告，氢气捕集通过设计氢气溢出分子与可逆温度和压力感应切换。

Pressure-induced Jahn-Teller switching in a Mn_(12) nanomagnet

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