Activation of H_2 by a highly distorted Rh~(II) complex with a new C_3-symmetric tripodal tetraphosphine ligand

Jeroen Wassenaar; Bas de Bruin; Maxime A. Siegler; Anthony L. Spek; Joost N. H. Reek; Jarl Ivar van der Vlugt

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Activation of H_2 by a highly distorted Rh~(II) complex with a new C_3-symmetric tripodal tetraphosphine ligand

机译：高度扭曲的Rh〜（II）配合物与新的C_3对称三脚架四膦配体的活化H_2

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摘要

Facile oxidation of a sterically encumbered Rh~I complex generates a stable Rh~(II) metalloradical species; the latter is able to activate H_2 under formation of the corresponding Rh~(III) complex.

机译：在空间上受阻的Rh〜I配合物的容易氧化会生成稳定的Rh〜（II）金属铁物种。后者能够在相应的Rh〜（III）配合物形成下活化H_2。

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《Chemical Communications》 |2010年第8期|1232-1234|共3页
作者
Jeroen Wassenaar; Bas de Bruin; Maxime A. Siegler; Anthony L. Spek; Joost N. H. Reek; Jarl Ivar van der Vlugt;
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Supramolecular & Homogeneous Catalysis Group,van't Hoff Institute for Molecular Sciences,University of Amsterdam, Nieuwe Achtergracht 166,1018 WV Amsterdam, the Netherlands;

Supramolecular & Homogeneous Catalysis Group,van't Hoff Institute for Molecular Sciences,University of Amsterdam, Nieuwe Achtergracht 166,1018 WV Amsterdam, the Netherlands;

Department of Crystal and Structural Chemistry,University of Utrecht, Padualaan 8, 3584 CH Utrecht,the Netherlands;

Department of Crystal and Structural Chemistry,University of Utrecht, Padualaan 8, 3584 CH Utrecht,the Netherlands;

Supramolecular & Homogeneous Catalysis Group,van't Hoff Institute for Molecular Sciences,University of Amsterdam, Nieuwe Achtergracht 166,1018 WV Amsterdam, the Netherlands;

Supramolecular & Homogeneous Catalysis Group,van't Hoff Institute for Molecular Sciences,University of Amsterdam, Nieuwe Achtergracht 166,1018 WV Amsterdam, the Netherlands;

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入库时间 2022-08-17 13:23:29

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Activation of H_2 by a highly distorted Rh~(II) complex with a new C_3-symmetric tripodal tetraphosphine ligand

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