Preparation of a tetraphenylethylene-based emitter: Synthesis, structure and optoelectronic properties of tetrakis(pentaphenylphenyl)ethylene

Vijay S. Vyas; Rajendra Rathore

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Preparation of a tetraphenylethylene-based emitter: Synthesis, structure and optoelectronic properties of tetrakis(pentaphenylphenyl)ethylene

机译：四苯基乙烯基发射体的制备：四（五苯基苯基）乙烯的合成，结构和光电性能

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Soluble tetrakis(pentaphenylphenyl)ethylene (1), prepared in three steps, allows non-emissive tetraphenylethylene (TPE) to turn into an emitter (Φ_F = 0.13) owing to the steric bulk of the four large hexaphenylbenzene propellers which hamper =C-Ph and C=C bond rotations in the TPE core.

机译：通过四个步骤制备的可溶性四（五苯基苯基）乙烯（1）可以使非发射四苯基乙烯（TPE）变成发射体（Φ_F= 0.13），这是因为四个大型六苯基苯螺旋桨的空间较大，妨碍了= C-Ph TPE核心中的C = C键旋转。

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《Chemical Communications》 |2010年第7期|1065-1067|共3页
作者
Vijay S. Vyas; Rajendra Rathore;
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Department of Chemistry, Marquette University, P.O. Box 1881, Milwaukee, Wisconsin-53233, USA;

Department of Chemistry, Marquette University, P.O. Box 1881, Milwaukee, Wisconsin-53233, USA;

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Preparation of a tetraphenylethylene-based emitter: Synthesis, structure and optoelectronic properties of tetrakis(pentaphenylphenyl)ethylene

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