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Halogen bonds as stabilizing interactions in a chiral self-assembled molecular monolayer

机译:卤素键作为手性自组装分子单层中的稳定相互作用

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摘要

We report the formation of highly-ordered self-assembled mono-layers of an achiral organic semiconductor molecule. STM results show spontaneous formation of very large single domains of ordered chiral monolayers. DFT calculations support the identification of halogen bonds as the primary interactions that steer molecular self-assembly, leading to organizational chirality.
机译:我们报告了非手性有机半导体分子的高度有序的自组装单层的形成。 STM结果显示有序手性单层非常大的单个域的自发形成。 DFT计算支持将卤素键识别为引导分子自组装并导致组织手性的主要相互作用。

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  • 来源
    《Chemical Communications》 |2011年第33期|p.9453-9455|共3页
  • 作者单位

    Department of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Str. West, Montreal, QC H3A 2K6, Canada Institut National de la Recherche Scientifique and Centre for Self-Assembled Chemical Structures, Universite du Quebec, 1650 boulevard Lionel-Boulet, Varennes, QC J3X 1S2, Canada;

    rnDepartment of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Str. West, Montreal, QC H3A 2K6, Canada;

    rnDepartment of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Str. West, Montreal, QC H3A 2K6, Canada Institut National de la Recherche Scientifique and Centre for Self-Assembled Chemical Structures, Universite du Quebec, 1650 boulevard Lionel-Boulet, Varennes, QC J3X 1S2, Canada;

    rnDepartment of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Str. West, Montreal, QC H3A 2K6, Canada Present address: Department of Chemistry, University of Ottawa, Ottawa, ON, Canada;

    rnInstitut National de la Recherche Scientifique and Centre for Self-Assembled Chemical Structures, Universite du Quebec, 1650 boulevard Lionel-Boulet, Varennes, QC J3X 1S2, Canada;

    rnDepartment of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Str. West, Montreal, QC H3A 2K6, Canada;

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  • 入库时间 2022-08-17 13:22:43

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