Access to unusual polycyclic spiro-enones from 2,2/-bis(allyloxy)-l,l/-binaphthyls using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen sequence

Estefania Piedra; Javier Francos; Noel Nebra; Francisco J. Suarez; Josefina Diez; Victorio Cadierno

首页> 外文期刊>Chemical Communications >Access to unusual polycyclic spiro-enones from 2,2/-bis(allyloxy)-l,l/-binaphthyls using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen sequence

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Access to unusual polycyclic spiro-enones from 2,2/-bis(allyloxy)-l,l/-binaphthyls using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen sequence

机译：使用Grubbs的催化剂从2,2 /-双（烯丙氧基）-1，l /-联萘类化合物中获得不寻常的多环螺烯烯酮：前所未有的一锅RCM /克莱森序列

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Treatment of 2,2'-bis(allyloxy)-l,l'-binaphthyls with the first-generation Grubbs' carbene under MW-irradiation results in the formation of new polycyclic spiro-enones through an unprecedented RCM/Claisen sequence.

机译：在MW辐射下用第一代Grubbs卡宾处理2,2'-双（烯丙氧基）-1，l'-联萘，通过前所未有的RCM / Claisen序列形成了新的多环螺烯烯。

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《Chemical Communications》 |2011年第27期|p.7866-7868|共3页
作者
Estefania Piedra; Javier Francos; Noel Nebra; Francisco J. Suarez; Josefina Diez; Victorio Cadierno;
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Departamento de Qulmica Orgdnica e Inorgdnica, IUQOEM,University of Oviedo, E-33006 Oviedo, Spain;

Departamento de Qulmica Orgdnica e Inorgdnica, IUQOEM,University of Oviedo, E-33006 Oviedo, Spain;

Departamento de Qulmica Orgdnica e Inorgdnica, IUQOEM,University of Oviedo, E-33006 Oviedo, Spain;

Departamento de Qulmica Orgdnica e Inorgdnica, IUQOEM,University of Oviedo, E-33006 Oviedo, Spain;

Departamento de Qulmica Orgdnica e Inorgdnica, IUQOEM,University of Oviedo, E-33006 Oviedo, Spain;

Departamento de Qulmica Orgdnica e Inorgdnica, IUQOEM,University of Oviedo, E-33006 Oviedo, Spain;

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2. Syntheses and reactions of (R)-(C10H6)(2)M-2 (M=SnMeCl2, SnMe2Cl SnMe(OTf)(2), SnMe2OTf, SiMe2I) as novel chiral 2,2 '-bis-metallic-1,1 '-binaphthyl catalysts [J] . Hoshi T., Shionoiri H., Katano M., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2002,第19期

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4. Access to unusual polycyclic spiro-enones from 2,2'-bis(allyloxy)-1,1'-binaphthyls using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen sequence [O] . Piedra Arroni Estefania, Francos Arias Javier, Nebra Muñiz Noel, 2011

机译：使用Grubbs的催化剂从2,2'-双（烯丙氧基）-1,1'-联萘获得不寻常的多环螺烯-烯酮：前所未有的一锅RCM / Claisen序列

Access to unusual polycyclic spiro-enones from 2,2/-bis(allyloxy)-l,l/-binaphthyls using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen sequence

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