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首页> 外文期刊>Chemical Communications >A luminescent gold(Ⅰ)-copper(Ⅰ) cluster with unprecedented carbon-centered trigonal prismatic hexagold
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A luminescent gold(Ⅰ)-copper(Ⅰ) cluster with unprecedented carbon-centered trigonal prismatic hexagold

机译：具有前所未有的以碳为中心的三棱柱六方金的发光金（Ⅰ）-铜（Ⅰ）簇

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摘要

An unprecedented trigonal prismatic (μ_6-C)Au_6 structure has been found in a novel gold(Ⅰ)-copper(Ⅰ) cluster with a hypercoordinated carbon, [CAu_6Cu_2(dppy)_6](BF_4)_4; the incorporation of copper ions enhances the rigidity and integrity of the cluster and turns on the bright red solution luminescence.
机译：在具有超配位碳[CAu_6Cu_2（dppy）_6]（BF_4）_4的新型金（Ⅰ）-铜（Ⅰ）团簇中发现了前所未有的三角棱柱形（μ_6-C）Au_6结构；铜离子的引入增强了簇的刚度和完整性，并开启了亮红色溶液的发光。

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  • 来源
    《Chemical Communications》 |2011年第16期|p.4739-4741|共3页
  • 作者

    Jian-Hua Jia; Jing-Xia Liang; Zhen Lei; Ze-Xing Cao; Quan-Ming Wang;

  • 作者单位

    State Key Lab of Physical Chemistry of Solid Surfaces,Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005,P. R. China;

    State Key Lab of Physical Chemistry of Solid Surfaces,Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005,P. R. China;

    State Key Lab of Physical Chemistry of Solid Surfaces,Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005,P. R. China;

    State Key Lab of Physical Chemistry of Solid Surfaces,Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005,P. R. China;

    State Key Lab of Physical Chemistry of Solid Surfaces,Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005,P. R. China;

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  • 入库时间 2022-08-17 13:22:18

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