{Mn_14W_48} aggregate: the perspective of isopolyanions as ligands

摘要

The assembly of a tetradeca-manganese magnetic cluster [Mn_14W_48O_192H_20]~(26-), containing two high spin Mn_7 cores and supported exclusively by isopolytungstate ligands, demonstrates the promising perspective of using "defect" iso polyanions as ligands/synthons to construct large aggregated structures and model the surface deposition of molecular magnets.