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Nitrosyl isomerism in amorphous Mn(TPP)(NO) solids

机译:非晶态Mn(TPP)(NO)固体中的亚硝基异构

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摘要

Reaction of NO with amorphous Mn(TPP) layers gives two Mn(TPP)(NO) isomers with linear and bent Mn-N-O geometries that reversibly interconvert with changes in temperature. DFT computations predict that the linear complex is the singlet ground state while the bent structure is a triplet state.
机译:NO与无定形Mn(TPP)层的反应产生了两个Mn(TPP)(NO)异构体,它们具有线性和弯曲的Mn-N-O几何形状,可随温度变化可逆地相互转换。 DFT计算预测线性复合体是单重态,而弯曲结构是三重态。

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  • 来源
    《Chemical Communications》 |2012年第99期|12088-12090|共3页
  • 作者单位

    Molecule Structure Research Center (MSRC), National Academy of Sciences, 0014, Yerevan, Armenia;

    Molecule Structure Research Center (MSRC), National Academy of Sciences, 0014, Yerevan, Armenia;

    Molecule Structure Research Center (MSRC), National Academy of Sciences, 0014, Yerevan, Armenia;

    Molecule Structure Research Center (MSRC), National Academy of Sciences, 0014, Yerevan, Armenia;

    Department of Chemistry, Lake Superior State University, Sault Sainte Marie, MI 49783, USA;

    Department of Chemistry, University of Leuven, B-3001 Heverlee, Belgium;

    Department of Chemistry, University of Leuven, B-3001 Heverlee, Belgium;

    Department of Chemistry and Biochemistry, University of California,Santa Barbara, CA 93106-9510, USA;

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  • 入库时间 2022-08-17 13:21:11

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