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首页> 外文期刊>Chemical Communications >Poly(polyoxometalate)s assembled by {Ni_6PW_9} units: from ring-shaped Ni_(24)-tetramers to rod-shaped Ni_(40)-octamers
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Poly(polyoxometalate)s assembled by {Ni_6PW_9} units: from ring-shaped Ni_(24)-tetramers to rod-shaped Ni_(40)-octamers

机译:由{Ni_6PW_9}单元组装而成的多金属氧酸盐:从环状Ni_(24)-四聚体到棒状Ni_(40)-八聚体

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摘要

Both structure-directing effect and synergistic-directing effect of PW_9O_(34) fragments result in two poly(polyoxotungstate)s (poly(POT)s) of the Ni_(24)-based tetramer with largest transition metal atoms among ring-shaped poly(POT) tetramers and the Ni_(40)-based poly(POT) octamer with the highest number of Ni ions among all known poly(POT)s to date, respectively.
机译:PW_9O_(34)片段的结构导向作用和协同导向作用均导致环状多聚体中具有最大过渡金属原子的Ni_(24)基四聚体的两个聚多聚钨酸盐(poly(POT)s) (POT)四聚体和迄今为止在所有已知聚(POT)中具有最高Ni离子数量的基于Ni_(40)的聚(POT)八聚体。

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  • 来源
    《Chemical Communications》 |2012年第77期|p.9658-9660|共3页
  • 作者单位

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences,Fuzhou, Fujian 350002, China;

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences,Fuzhou, Fujian 350002, China;

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences,Fuzhou, Fujian 350002, China;

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences,Fuzhou, Fujian 350002, China,DOE Key Laboratory of Cluster Science, School of Chemistry,Beijing Institute of Technology, Beijing 100081, China;

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