Iridium-catalyzed reaction of enones with alcohols affording 1,3-diketones

Yasushi Obora; Kazuhiro Nakamura; Shintaro Hatanaka

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Iridium-catalyzed reaction of enones with alcohols affording 1,3-diketones

机译：铱与醇催化的烯酮反应生成1,3-二酮

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An iridium-catalyzed coupling reaction of alcohols with enones has been successfully developed providing access to 1,3-diketones with high selectivity in good yields. This reaction provides an atom-economical route to 1,3-diketones from readily available alcohols.

机译：醇与烯酮的铱催化的偶联反应已成功开发，可以高收率获得高选择性的1,3-二酮。该反应提供了从容易获得的醇制取1,3-二酮的原子经济途径。

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《Chemical Communications》 |2012年第53期|p.6720-6722|共3页
作者
Yasushi Obora; Kazuhiro Nakamura; Shintaro Hatanaka;
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Department of Chemistry and Materials Engineering,Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan;

Department of Chemistry and Materials Engineering,Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan;

Department of Chemistry and Materials Engineering,Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan;

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入库时间 2022-08-17 13:20:53

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机译：DBU催化的核心核心的核心反应，用1,3-二酮和随后的碘介导的聚合酚的加合物转化
2. Variations in the Blaise Reaction: Conceptually New Synthesis of 3-Amino Enones and 1,3-Diketones [J] . Rao H. Surya Prakash, Muthanna Nandurka European journal of organic chemistry . 2015,第7期

机译：Blaise反应的变化：概念上新合成的3-氨基酮和1,3-二酮
3. New Hybrid-type Squaramide-Fused Amino Alcohol Organocatalystfor Enantioselective Domino Michael Addition/Cyclization Reactionof Oxoindolines with Cyclic 1,3-Diketones [J] . Madhu Chennapuram, Isiaka Alade Owolabi, Chigusa Seki, ACS Omega . 2018,第9期

机译：新型杂合型方酰胺熔融氨基醇有机催化剂，用于对映选择性多米诺·迈克尔加氧/吲哚啉与环状1，3-二酮的环化反应
4. Efficient Synthesis of 1,3-Diketones by the RuHCl(CO)(PPh_3)_3-Catalyzed Addition of Aldehydes to Enones [C] . Sohei Omura, Takashi Doi, Satoshi Minamino Symposium on Organometallic Chemistry . 2006

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5. REACTIONS OF CYCLIC 1,3 DIKETONES WITH HYDROZINE: THE PREPARATION OF DERIVATIVES OF CINNOLINO(5,4,3-CDE) CINNOLINE, PYRIDAZINE AND PYRIDAZIONO(4,5-D)PYRIDAZINE. [D] . UNGLAUBE, JAMES MATHEW. 1968

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6. Enantioselective Iridium-Catalyzed Vinylogous Reformatsky-Aldol Reaction from the Alcohol Oxidation Level: Linear Regioselectivity by Way of Carbon-Bound Enolates [O] . Abbas Hassan, Jason R. Zbieg, Prof. Michael J. Krische -1

机译：来自醇氧化水平的对映选择性铱催化的乙烯基富集性 - 醛醇反应：通过碳结合的烯丙基线性区域选择性
7. Cyclocondensation of Hydroxylamine with 1,3-Bis(het)arylmonothio 1,3-Diketones and 1,3-Bis(het)aryl-3-(methylthio)-2-propenones: Synthesis of 3,5-Bis(het)arylisoxazoles with Complementary Regioselectivity [O] . Raghava B., Parameshwarappa G., Acharya Anand, 2014

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Iridium-catalyzed reaction of enones with alcohols affording 1,3-diketones

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