Zwitterionic half-sandwich Rh and Ir complexes containing a diphosphine nido-carborane ligand: synthesis, structure transformation and application in H_2 activation

Zi-Jian Yao; Xian-Kuan Huo; Guo-Xin Jin

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Zwitterionic half-sandwich Rh and Ir complexes containing a diphosphine nido-carborane ligand: synthesis, structure transformation and application in H_2 activation

机译：含二膦酰基-碳环烷配体的两性离子半三明治Rh和Ir配合物：合成，结构转化及其在H_2活化中的应用

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Several novel zwitterionic half-sandwich complexes and pseudo-closo metallacarboranes based on 1,2-(PPh_2)_2-1,2-C_2B_(10)H_(10) were successfully prepared, and further study proved that some of them can activate H_2 to form the metal hydride complexes Cp*M(H)(7,8-(PPh_2)_2-7,8-C_2B_9H_(10)) (M = Rh, Ir).

机译：成功制备了几种新型的基于1,2-（PPh_2）_2-1,2-C_2B_（10）H_（10）的两性离子半三明治复合物和假-氯金属碳硼烷，并进一步研究证明它们中的一些可以激活H_2形成金属氢化物配合物Cp * M（H）（7,8-（PPh_2）_2-7,8-C_2B_9H_（10））（M = Rh，Ir）。

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《Chemical Communications》 |2012年第53期|p.6714-6716|共3页
作者
Zi-Jian Yao; Xian-Kuan Huo; Guo-Xin Jin;
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Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University,Shanghai, 200433, P. R. China;

Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University,Shanghai, 200433, P. R. China;

Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University,Shanghai, 200433, P. R. China,State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry, Chinese Academy of Science,Shanghai, 200032, P. R. China;

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Zwitterionic half-sandwich Rh and Ir complexes containing a diphosphine nido-carborane ligand: synthesis, structure transformation and application in H_2 activation

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